Johannes van der Waals

Johannes Diderik van der Waals (Dutch: [joːˈɦɑnəz ˈdidərɪk fɑn dər ˈʋaːls] ; 23 November 1837 – 8 March 1923) was a Dutch theoretical physicist who received the Nobel Prize in Physics in 1910 "for his work on the equation of state for gases and liquids." Van der Waals started his career as a schoolteacher, before becoming the first physics professor of the University of Amsterdam when its status was upgraded to Municipal University in 1877. His name is primarily associated with the van der Waals equation, an equation of state that describes the behavior of gases and their condensation to the liquid phase. His name is also associated with van der Waals forces (forces between stable molecules), with van der Waals molecules (small molecular clusters bound by van der Waals forces), and with the van der Waals radius (size of molecules). James Clerk Maxwell once said that, "there can be no doubt that the name of Van der Waals will soon be among the foremost in molecular science." In his 1873 thesis, Van der Waals noted the non-ideality of real gases and attributed it to the existence of intermolecular interactions. He introduced the first equation of state derived by the assumption of a finite volume occupied by the constituent molecules. Spearheaded by Ernst Mach and Wilhelm Ostwald, a strong philosophical current that denied the existence of molecules arose towards the end of the 19th century. The molecular existence was considered unproven and the molecular hypothesis unnecessary. At the time Van der Waals's thesis was written (1873), the molecular structure of fluids had not been accepted by most physicists, and liquid and vapor were often considered as chemically distinct. But Van der Waals's work affirmed the reality of molecules and allowed an assessment of their size and attractive strength. His new formula revolutionized the study of equations of state. By comparing his equation of state with experimental data, Van der Waals was able to obtain estimates for the actual size of molecules and the strength of their mutual attraction. The effect of Van der Waals's work on molecular physics in the 20th century was direct and fundamental. By introducing parameters characterizing molecular size and attraction in constructing his equation of state, Van der Waals set the tone for modern molecular science. That molecular aspects such as size, shape, attraction, and multipolar interactions should form the basis for mathematical formulations of the thermodynamic and transport properties of fluids is presently considered an axiom. With the help of the Van der Waals's equation of state, the critical-point parameters of gases could be accurately predicted from thermodynamic measurements made at much higher temperatures. Nitrogen, oxygen, hydrogen, and helium subsequently succumbed to liquefaction. Heike Kamerlingh Onnes was significantly influenced by the pioneering work of Van der Waals. In 1908, Onnes became the first to make liquid helium; this led directly to his 1911 discovery of superconductivity.

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